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Silicone (VMQ)

Vinyl-methyl-siloxane rubber — an inorganic elastomer based on a silicon-oxygen backbone (Si-O-Si) rather than the carbon backbone of organic rubbers, providing the widest useful temperature range of any commercial elastomer: -60 to +230°C continuous (special grades to +300°C). Key properties: excellent biocompatibility (FDA 21 CFR 177.2600, USP Class VI), non-toxic and odorless, outstanding ozone and UV resistance (essentially permanent outdoor exposure), excellent electrical insulation, and high-temperature compression set resistance. ASTM D2000 classification: FC/FE/GE depending on grade. Limitations: low tensile strength (5-10 MPa, weakest of common elastomers), poor abrasion resistance, poor resistance to hydrocarbon solvents and steam, and relatively high cost ($8-25/kg). Applications: food-grade seals and gaskets (bakery oven conveyors, beverage dispensers), medical devices (tubing, implants), automotive spark plug boots, LED encapsulation, high-temperature oven gaskets, baby products, and electrical insulation. Grades: standard VMQ, fluorosilicone FVMQ (fuel resistance + temperature), and liquid silicone (LSR, for injection molding). Manufacturers: Wacker (Elastosil), Dow (Silastic), Shin-Etsu, Momentive.

What you need to know

  • Vinyl-methyl-siloxane rubber — an inorganic elastomer based on a silicon-oxygen backbone (Si-O-Si) rather than the carbon backbone of organic rubbers, providing the widest useful temperature range of any commercial elastomer: -60 to +230°C continuous (special grades to +300°C).
  • Key properties: excellent biocompatibility (FDA 21 CFR 177.2600, USP Class VI), non-toxic and odorless, outstanding ozone and UV resistance (essentially permanent outdoor exposure), excellent electrical insulation, and high-temperature compression set resistance.
  • ASTM D2000 classification: FC/FE/GE depending on grade.
  • Limitations: low tensile strength (5-10 MPa, weakest of common elastomers), poor abrasion resistance, poor resistance to hydrocarbon solvents and steam, and relatively high cost ($8-25/kg).
  • Applications: food-grade seals and gaskets (bakery oven conveyors, beverage dispensers), medical devices (tubing, implants), automotive spark plug boots, LED encapsulation, high-temperature oven gaskets, baby products, and electrical insulation.

Full definition

Silicone rubber, specifically vinyl-methyl-siloxane (VMQ), is a unique type of elastomer characterized by its silicon-oxygen backbone (Si-O-Si). Unlike traditional organic rubbers that rely on a carbon backbone, VMQ offers an extraordinary temperature range, functioning effectively in environments from -60°C to +230°C, with special grades capable of withstanding temperatures up to +300°C. This property makes it particularly valuable in applications where high thermal stability is essential. VMQ is classified under ASTM D2000 as FC/FE/GE, which indicates its varying resistance properties based on specific grades. The biocompatibility of VMQ rubber is another critical advantage, compliant with FDA standards (21 CFR 177.2600) and recognized as USP Class VI, making it suitable for medical and food-grade applications. This material's non-toxic and odorless nature further enhances its appeal in sensitive environments, such as food processing and healthcare.

Another remarkable feature of VMQ is its resistance to environmental factors such as ozone and UV radiation, allowing for prolonged outdoor use without significant degradation. The electrical insulation properties of silicone rubber also make it a preferred choice for applications requiring non-conductive materials, such as in electrical connectors and automotive components. However, VMQ is not without its limitations. It possesses relatively low tensile strength, typically ranging from 5 to 10 MPa, which is weaker compared to other common elastomers. Additionally, VMQ exhibits poor abrasion resistance and is not ideal for environments with hydrocarbon solvents or steam exposure. Despite these drawbacks, the versatility and performance characteristics of VMQ make it a popular choice across various industries.

Silicone rubber is widely utilized in food-grade seals, gaskets for bakery oven conveyors, and beverage dispensers, demonstrating its safety and durability in food applications. In the medical field, it is used for tubing and implants, ensuring patient safety while maintaining high performance. The automotive industry employs VMQ for spark plug boots and high-temperature gaskets, while LED encapsulation applications benefit from its excellent thermal stability and electrical insulation properties. Liquid silicone rubber (LSR) is also gaining traction for injection molding, offering precise and intricate designs for various applications. Key manufacturers of VMQ include Wacker (Elastosil), Dow (Silastic), Shin-Etsu, and Momentive, which provide a range of products suited to different industrial needs.

What you need to know

  • VMQ operates effectively at temperatures from -60°C to +230°C, with special grades reaching up to +300°C.
  • It is classified under ASTM D2000 as FC/FE/GE, indicating its resistance properties based on specific grades.
  • VMQ is compliant with FDA standards (21 CFR 177.2600) and recognized as USP Class VI for biocompatibility.
  • The tensile strength of VMQ typically ranges from 5 to 10 MPa, making it weaker than other common elastomers.
  • Applications include food-grade seals, medical devices, automotive components, and electrical insulation.

Industrial applications

  • 1Food-grade seals and gaskets for bakery oven conveyors and beverage dispensers.
  • 2Medical devices such as tubing and implants due to its biocompatibility.
  • 3Automotive spark plug boots that require high-temperature resistance.
  • 4LED encapsulation for thermal stability and electrical insulation.
  • 5High-temperature oven gaskets ensuring durability in extreme conditions.

Common mistakes

  • Using VMQ in applications involving hydrocarbon solvents, leading to material degradation.
  • Overlooking the tensile strength limitations of VMQ, resulting in failure under excessive load.
  • Neglecting to consider temperature ratings for specific grades, risking performance in high-heat environments.
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Pro tip

When selecting VMQ for applications, ensure to choose the specific grade that matches your environmental exposure and mechanical requirements.

Technical standards

  • FDA 21 CFR 177.2600 - Regulates materials that may come into contact with food.
  • ASTM D2000 - Classification system for rubber materials in industrial applications.

Suppliers of industrial materials in Mexico

Applicable standards

ASTM D2000