Full definition
Styrene-Butadiene Rubber (SBR) is a synthetic elastomer that has become the most widely produced rubber in the world, with an annual production of approximately 6 million tonnes. Initially developed during World War II as a substitute for natural rubber, SBR is valued for its excellent balance of properties, making it a versatile choice in various industrial applications. The typical styrene content in SBR is around 23.5%, which influences the material's hardness and flexibility. Higher styrene levels can enhance hardness and stiffness but can compromise resilience and low-temperature performance. As a result, SBR is commonly utilized in applications where these properties are essential, such as in tire manufacturing and industrial components.
SBR exhibits a hardness range of 40-90 Shore A and tensile strength between 10-25 MPa when reinforced with carbon black. This capability allows SBR to stretch up to 300-600% before breaking, providing significant elongation properties. However, compared to natural rubber (NR), SBR's resilience is lower, averaging between 50-60%, while NR can achieve around 80%. The classification of SBR under ASTM D2000 includes standard grades (AA) and higher performance grades (BA), which further define the material's use in demanding applications.
There are two primary types of SBR: emulsion SBR (E-SBR), which is typically used for general products, and solution SBR (S-SBR), which is preferred for applications requiring improved rolling resistance, such as modern tire treads. Despite its many benefits, SBR has limitations, particularly in its resistance to oil and ozone, often requiring the use of antiozonant additives to enhance durability in specific environments. Common applications include tire treads and sidewalls, industrial rubber sheets, flooring, conveyor belt covers, gaskets, footwear soles, hose covers, and roll coverings. Due to its flexibility and cost-effectiveness, SBR is frequently blended with natural rubber (NR) or butyl rubber (BR) to optimize performance characteristics for various applications.