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HNBR

Hydrogenated Nitrile Butadiene Rubber — a premium grade of NBR in which the polymer backbone is catalytically hydrogenated (saturating the C=C double bonds), dramatically improving heat resistance, ozone resistance, and aging stability while retaining the excellent oil and fuel resistance of standard NBR. Continuous temperature: -30 to +150°C (vs -30 to +100°C for NBR). Ozone resistance: excellent (vs poor for NBR). Tensile strength: 20-30 MPa (among the highest of all elastomers). Abrasion resistance: outstanding. ACN content: 17-50% (same trade-off as NBR — higher ACN = better oil resistance, lower flexibility). Per ASTM D2000 classification: DH. Primary applications: automotive timing belt tooth compound (the dominant application), serpentine belt backing, high-performance shaft seals, hydraulic seals for high-temperature service, and downhole oilfield seals. Cost: 3-5x standard NBR, justified by 2-3x service life and superior performance. Brands: Zeon (Zetpol), Lanxess (Therban).

What you need to know

  • Hydrogenated Nitrile Butadiene Rubber — a premium grade of NBR in which the polymer backbone is catalytically hydrogenated (saturating the C=C double bonds), dramatically improving heat resistance, ozone resistance, and aging stability while retaining the excellent oil and fuel resistance of standard NBR.
  • Continuous temperature: -30 to +150°C (vs -30 to +100°C for NBR).
  • Ozone resistance: excellent (vs poor for NBR).
  • Tensile strength: 20-30 MPa (among the highest of all elastomers).
  • Abrasion resistance: outstanding.

Full definition

Hydrogenated Nitrile Butadiene Rubber (HNBR) is a specialized elastomer that stems from the hydrogenation of standard Nitrile Butadiene Rubber (NBR). This process saturates the unsaturated C=C double bonds in the polymer backbone, resulting in a material that boasts significantly enhanced thermal stability, ozone resistance, and aging properties, while still maintaining the exceptional oil and fuel resistance that NBR is known for. The continuous service temperature range for HNBR spans from -30°C to +150°C, which is an improvement over NBR's range of -30°C to +100°C. This enhanced temperature capability allows HNBR to be effective in more demanding environments, making it suitable for various industrial applications.

The mechanical properties of HNBR are impressive, with tensile strengths ranging from 20 to 30 MPa, placing it among the top elastomers in terms of strength. This high tensile strength, coupled with outstanding abrasion resistance, makes HNBR an ideal choice for applications where durability and resilience are critical. The Acrylonitrile (ACN) content in HNBR typically ranges from 17% to 50%. Higher ACN levels correlate with better oil resistance but may compromise flexibility, creating a trade-off that engineers must consider when selecting HNBR for specific applications.

HNBR is classified under ASTM D2000 as a DH material, which denotes its suitability for high-performance applications. Its primary use is in automotive applications, particularly in timing belt tooth compounds, where it provides the necessary durability and longevity. Additionally, HNBR is utilized in serpentine belt backing, high-performance shaft seals, hydraulic seals for applications requiring high-temperature service, and downhole seals in oilfields, where the combination of oil resistance and thermal stability is paramount. Although HNBR is priced 3-5 times higher than standard NBR, the investment is justified by its 2-3 times longer service life and superior performance characteristics.

What you need to know

  • HNBR offers continuous temperature resistance from -30°C to +150°C, outperforming standard NBR.
  • Tensile strength for HNBR ranges from 20 to 30 MPa, making it one of the strongest elastomers available.
  • HNBR demonstrates excellent ozone resistance compared to NBR's poor performance.
  • The ACN content in HNBR affects oil resistance and flexibility, typically ranging from 17% to 50%.
  • HNBR is classified as a DH material under ASTM D2000, suitable for high-performance applications.

Industrial applications

  • 1Automotive timing belts where durability and heat resistance are critical.
  • 2Serpentine belts in high-performance engines requiring flexibility and strength.
  • 3Hydraulic seals in systems operating under high temperatures and pressures.
  • 4Downhole oilfield seals that must withstand extreme conditions and exposure to oil.
  • 5High-performance shaft seals in machinery exposed to oils and high temperatures.

Common mistakes

  • Selecting HNBR with too high ACN content for applications requiring flexibility, leading to premature failure.
  • Overlooking the temperature ranges specified for HNBR, potentially leading to material degradation.
  • Assuming HNBR is a direct drop-in replacement for NBR without considering the differences in properties and performance.
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Pro tip

When choosing HNBR for specific applications, carefully assess the ACN content and temperature requirements to ensure optimal performance.

Technical standards

  • ASTM D2000 – Standard Classification System for Rubber Products in Automotive Applications, defining the properties and quality standards for HNBR.

Suppliers of industrial materials in Mexico

Applicable standards

ASTM D2000