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Materiales

Nylon (Polyamide)

A family of semi-crystalline engineering thermoplastics known for excellent mechanical strength, wear resistance, toughness, and moderate heat resistance. Major grades: PA6 (cast or extruded, good all-round properties, tensile 70-85 MPa, economical), PA66 (higher melting point 260°C vs 220°C, better heat resistance, slightly stronger), PA12 (lowest moisture absorption, best chemical resistance, most flexible, for fuel lines), PA46 (highest heat resistance, for under-hood automotive). Key properties: self-lubricating (low COF 0.2-0.4 against steel), high fatigue endurance, good chemical resistance to hydrocarbons and weak alkalis. Limitation: hygroscopic — absorbs 2-8% moisture depending on grade, causing dimensional change and property reduction (PA12 least affected at 1.4%). Per ASTM D4066. Applications: gears, bearings, bushings, bearing cages, cable ties, chain guides, conveyor belt weft yarns, rollers, and structural components. Glass-fiber reinforced grades (GF30, GF50) significantly increase stiffness and strength. Brands: DuPont Zytel, BASF Ultramid, DSM Akulon.

What you need to know

  • A family of semi-crystalline engineering thermoplastics known for excellent mechanical strength, wear resistance, toughness, and moderate heat resistance.
  • Major grades: PA6 (cast or extruded, good all-round properties, tensile 70-85 MPa, economical), PA66 (higher melting point 260°C vs 220°C, better heat resistance, slightly stronger), PA12 (lowest moisture absorption, best chemical resistance, most flexible, for fuel lines), PA46 (highest heat resistance, for under-hood automotive).
  • Key properties: self-lubricating (low COF 0.2-0.4 against steel), high fatigue endurance, good chemical resistance to hydrocarbons and weak alkalis.
  • Limitation: hygroscopic — absorbs 2-8% moisture depending on grade, causing dimensional change and property reduction (PA12 least affected at 1.4%).
  • Per ASTM D4066.

Full definition

Nylon, also known as polyamide, is a versatile family of semi-crystalline engineering thermoplastics that exhibit exceptional mechanical strength and wear resistance. These materials are known for their toughness and moderate heat resistance, making them suitable for a wide range of industrial applications. Among the various grades of nylon, PA6 is recognized for its good all-round properties and economical pricing, with a tensile strength ranging from 70 to 85 MPa. This grade is often utilized in applications where balance between cost and performance is essential. In contrast, PA66 offers a higher melting point of 260°C compared to PA6’s 220°C, making it a better choice for applications requiring enhanced heat resistance and strength. Other grades like PA12 are favored for their low moisture absorption, with only 1.4%, which significantly minimizes dimensional changes and property degradation, particularly in environments where exposure to fluids is common, such as fuel lines.

The semi-crystalline structure of nylon contributes to its self-lubricating properties, exhibiting a low coefficient of friction (COF) of 0.2 to 0.4 against steel, which enhances its performance in dynamic applications. Furthermore, nylon materials have high fatigue endurance and good chemical resistance to hydrocarbons and weak alkalis, allowing them to maintain integrity in challenging environments. However, nylon is hygroscopic, meaning it can absorb moisture ranging from 2% to 8% depending on the grade, which can lead to dimensional changes and reduced mechanical properties. This characteristic particularly affects PA6 and PA66, while PA12 remains the least affected.

Glass-fiber reinforced nylon grades, such as GF30 and GF50, significantly enhance stiffness and strength, making them ideal for load-bearing applications. Common uses of nylon include gears, bearings, bushings, bearing cages, cable ties, chain guides, conveyor belt weft yarns, rollers, and various structural components. These attributes make nylon a preferred material in automotive, aerospace, and industrial manufacturing sectors, where performance, durability, and weight savings are critical factors.

What you need to know

  • Nylon (Polyamide) is a semi-crystalline thermoplastic known for its mechanical strength and wear resistance.
  • Common grades include PA6 (tensile strength 70-85 MPa), PA66 (higher melting point at 260°C), and PA12 (low moisture absorption at 1.4%).
  • Nylon exhibits a low coefficient of friction (0.2-0.4), making it suitable for dynamic applications.
  • Hygroscopic nature leads to moisture absorption of 2-8%, affecting dimensional stability and properties.
  • Reinforced grades like GF30 and GF50 increase strength and stiffness for heavy-duty applications.

Industrial applications

  • 1Gears and bearings in automotive applications for improved durability.
  • 2Bushings and bearing cages in machinery where low friction is essential.
  • 3Cable ties used in electrical and mechanical assemblies for secure fastening.
  • 4Chain guides in conveyor systems to enhance efficiency and reduce wear.
  • 5Structural components in aerospace designs where weight and strength are critical.

Common mistakes

  • Neglecting the hygroscopic nature of nylon during design, leading to unexpected dimensional changes.
  • Using nylon grades not suited for specific chemical environments, risking material degradation.
  • Overlooking the benefits of glass-fiber reinforcement for applications requiring high strength.
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Pro tip

When selecting nylon for applications, consider the operating environment and potential moisture exposure to choose the appropriate grade.

Technical standards

  • ASTM D4066 - Standard Specification for Nylon (Polyamide) Plastic.
  • ISO 1874 - Determination of the properties of nylon and other polyamide plastics.

Suppliers of industrial materials in Mexico

Applicable standards

ASTM D4066.