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Synthetic Rubber

Any elastomer produced by chemical polymerization of petroleum-derived monomers, as opposed to natural rubber harvested from Hevea brasiliensis trees. Global synthetic rubber production: ~15 million tonnes/year (roughly equal to NR). Major types and their key attributes: SBR (general purpose, lowest cost), BR/polybutadiene (highest resilience, tire treads), NBR/nitrile (oil resistance, seals), EPDM (weather/ozone/steam resistance), CR/neoprene (balanced properties, flame resistance), IIR/butyl (gas impermeability, damping), silicone VMQ (extreme temperature range), FKM/fluorocarbon (chemical/heat resistance), and PU/polyurethane (highest abrasion/mechanical strength). Each synthetic rubber was developed to address specific limitations of NR: oil resistance (NBR), ozone resistance (EPDM, CR), heat resistance (FKM, silicone), gas barrier (IIR), etc. Raw material: petroleum-derived monomers (butadiene, styrene, acrylonitrile, ethylene, propylene, chloroprene, etc.). Polymerization: emulsion (water-based), solution (solvent-based), or gas-phase processes. Per ASTM D1418 for nomenclature and classification of rubber types.

What you need to know

  • Any elastomer produced by chemical polymerization of petroleum-derived monomers, as opposed to natural rubber harvested from Hevea brasiliensis trees.
  • Global synthetic rubber production: ~15 million tonnes/year (roughly equal to NR).
  • Major types and their key attributes: SBR (general purpose, lowest cost), BR/polybutadiene (highest resilience, tire treads), NBR/nitrile (oil resistance, seals), EPDM (weather/ozone/steam resistance), CR/neoprene (balanced properties, flame resistance), IIR/butyl (gas impermeability, damping), silicone VMQ (extreme temperature range), FKM/fluorocarbon (chemical/heat resistance), and PU/polyurethane (highest abrasion/mechanical strength).
  • Each synthetic rubber was developed to address specific limitations of NR: oil resistance (NBR), ozone resistance (EPDM, CR), heat resistance (FKM, silicone), gas barrier (IIR), etc.
  • Raw material: petroleum-derived monomers (butadiene, styrene, acrylonitrile, ethylene, propylene, chloroprene, etc.).

Full definition

Synthetic rubber is a category of elastomers manufactured through the chemical polymerization of petroleum-derived monomers, distinguishing it from natural rubber sourced from the Hevea brasiliensis tree. With global production figures approximating 15 million tonnes annually, synthetic rubber accounts for nearly half of the total rubber supply worldwide. Its development has been crucial to meet specific performance criteria that natural rubber cannot address effectively. Each type of synthetic rubber is designed with particular properties that suit various industrial applications, making them essential in sectors such as automotive, construction, and consumer goods.

The major types of synthetic rubber include Styrene-Butadiene Rubber (SBR), which is known for its cost-effectiveness and versatility, making it ideal for various general-purpose applications. Polybutadiene Rubber (BR) offers exceptional resilience, predominantly utilized in tire treads due to its ability to withstand wear and tear. Nitrile Butadiene Rubber (NBR) is famous for its oil resistance, making it an excellent choice for seals and gaskets. Ethylene Propylene Diene Monomer (EPDM) exhibits outstanding resistance to weather, ozone, and steam, frequently used in roofing and automotive seals. Neoprene (CR) combines balanced properties, including flame resistance, making it suitable for a wide range of applications from wetsuits to industrial adhesives.

Other specialized types include Butyl Rubber (IIR), known for its gas impermeability and vibration dampening capabilities, and Fluoroelastomer (FKM), which withstands high temperatures and chemical exposure. Silicone rubber (VMQ) can endure extreme temperature ranges, making it ideal for seals in high-temperature environments. Finally, Polyurethane (PU) boasts the highest abrasion and mechanical strength, utilized in applications requiring durability and resilience. The production methods for synthetic rubber involve different processes, including emulsion, solution, and gas-phase polymerization, each chosen based on the desired properties and performance metrics of the final product. The nomenclature and classification of these rubber types are standardized under ASTM D1418, ensuring consistency across the industry.

What you need to know

  • What you need to know:
  • Synthetic rubber production reaches ~15 million tonnes/year, equal to natural rubber.
  • Types include SBR (general purpose), NBR (oil resistance), and EPDM (ozone resistance).
  • Polybutadiene (BR) is primarily used in tire manufacturing due to its resilience.
  • Production methods include emulsion, solution, and gas-phase processes.
  • ASTM D1418 provides nomenclature and classification for rubber types.

Industrial applications

  • 1Automotive industry for tires and seals, utilizing SBR and NBR.
  • 2Construction materials such as roofing membranes made from EPDM.
  • 3Consumer goods including footwear and sports equipment using CR and PU.
  • 4Industrial applications for gaskets and hoses leveraging NBR's oil resistance.
  • 5High-temperature applications where silicone rubber is essential for seals.

Common mistakes

  • Failing to select the appropriate rubber type for specific environmental conditions.
  • Neglecting to consider the effects of temperature and chemical exposure on rubber performance.
  • Using synthetic rubber outside its specified operational limits, leading to premature failure.
  • Overlooking the importance of proper storage conditions for synthetic rubber materials.
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Pro tip

Always evaluate the specific application requirements and environmental factors when selecting synthetic rubber to ensure optimal performance.

Technical standards

  • ASTM D1418 - Standard Classification for Rubber Types, providing guidelines for nomenclature and classification.

Suppliers of industrial rubber in Mexico

Applicable standards

ASTM D1418