Full definition
Silicone rubber, known chemically as VMQ (Vinyl Methyl Silicone), is a versatile inorganic elastomer characterized by its silicon-oxygen polymer backbone (polysiloxane). This unique structure allows silicone rubber to maintain its elasticity and mechanical properties over an exceptionally wide temperature range, from -60°C to +230°C under continuous use, with certain special grades extending this range from -100°C to +300°C. The stability of the Si-O bond, which is more resilient than the C-C bonds found in organic rubbers, contributes to silicone's resistance to thermal degradation, oxidative damage, and UV exposure, making it an ideal choice for applications requiring prolonged outdoor exposure and extreme temperature performance.
The properties of silicone rubber extend beyond temperature tolerance. It is biocompatible, classified under FDA and USP Class VI, meaning it is non-toxic, odorless, and tasteless, which is crucial for applications in the food and medical sectors. Its excellent ozone and weathering resistance ensure durability even in harsh environmental conditions. Furthermore, silicone exhibits outstanding electrical insulation properties, boasting a dielectric strength ranging between 15-25 kV/mm, making it suitable for high-voltage applications. One notable advantage is its low compression set at extreme temperatures, which allows it to maintain its shape and sealing effectiveness over time.
However, silicone rubber does have limitations. It has the lowest tensile strength among common elastomers, typically ranging from 5-10 MPa, and possesses poor abrasion resistance. Additionally, it can be vulnerable to steam and certain hydrocarbon solvents, which may limit its applications in some environments. The cost of silicone rubber is also relatively higher, ranging from $8 to $25 per kilogram, which can influence its selection for various projects. Silicone rubber is available in different forms, primarily solid HCR (high consistency rubber) which is compression or extrusion molded, and liquid LSR (liquid silicone rubber) that is typically used in two-component injection molding processes.