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ECO Rubber

Epichlorohydrin rubber — a specialty elastomer offering an excellent balance of fuel/oil resistance, ozone resistance, low gas permeability, and low-temperature flexibility in a single polymer. Three subtypes: CO (homopolymer, best oil/fuel resistance), ECO (copolymer with ethylene oxide, best low-temperature flexibility to -40°C), and GECO (terpolymer, cure-site monomer for peroxide cure). Temperature range: -40 to +135°C (ECO type) or -20 to +150°C (CO type). Gas permeability: 3-10x lower than NBR, making it excellent for fuel system diaphragms and bladders. Chemical resistance: good to mineral oils, fuels, ozone, and dilute acids; poor to ketones and esters. ASTM D2000 classification: CH/DE. Applications: automotive fuel hoses, fuel sender unit seals, diaphragms, air intake boots, and oil-resistant industrial gaskets. Positioned between NBR (cheaper but less ozone/heat resistant) and FKM (more chemical resistant but 5-10x more expensive). Suppliers: Zeon (Hydrin), Osaka Soda.

What you need to know

  • Epichlorohydrin rubber — a specialty elastomer offering an excellent balance of fuel/oil resistance, ozone resistance, low gas permeability, and low-temperature flexibility in a single polymer.
  • Three subtypes: CO (homopolymer, best oil/fuel resistance), ECO (copolymer with ethylene oxide, best low-temperature flexibility to -40°C), and GECO (terpolymer, cure-site monomer for peroxide cure).
  • Temperature range: -40 to +135°C (ECO type) or -20 to +150°C (CO type).
  • Gas permeability: 3-10x lower than NBR, making it excellent for fuel system diaphragms and bladders.
  • Chemical resistance: good to mineral oils, fuels, ozone, and dilute acids; poor to ketones and esters.

Full definition

ECO rubber, a copolymer of epichlorohydrin and ethylene oxide, is a specialized elastomer that provides a remarkable balance of properties suitable for various demanding applications. This material is particularly known for its excellent resistance to fuels and oils, making it a preferred choice in the automotive and industrial sectors. Its temperature range allows for operation in environments from -40°C to +135°C, ensuring reliability in both cold and hot conditions. The low gas permeability of ECO rubber, which is 3-10 times lower than that of nitrile rubber (NBR), enhances its performance in applications such as fuel system diaphragms and bladders, where leakage can lead to significant issues. The three main subtypes of epichlorohydrin rubber include CO, which offers the best oil and fuel resistance as a homopolymer, ECO itself for its superior low-temperature flexibility, and GECO, a terpolymer designed for peroxide curing processes.

In terms of chemical resistance, ECO rubber performs well against mineral oils, fuels, dilute acids, and ozone, although it exhibits poor resistance to ketones and esters. This makes it less suitable for environments where these chemicals are prevalent. According to ASTM D2000, ECO rubber falls under classifications CH and DE, indicating its suitability for various industrial applications. Its positioning in the market is strategic, being more affordable than FKM (fluoroelastomers) while offering better performance than NBR. This balance makes it an attractive option for manufacturers looking to optimize performance without incurring high material costs.

Applications of ECO rubber are diverse, particularly in the automotive industry, where it is utilized in fuel hoses, seals for fuel sender units, air intake boots, and various gaskets that require resistance to oil and fuel. In industrial settings, its properties lend themselves well to the production of gaskets and diaphragms that must withstand harsh conditions. The versatility and resilience of ECO rubber make it a valuable material for engineers and procurement managers seeking reliable solutions for fuel and oil resistance in their operations.

What you need to know

  • ECO rubber is a copolymer with ethylene oxide, providing excellent low-temperature flexibility down to -40°C.
  • It has a temperature range of -40 to +135°C, making it suitable for various automotive applications.
  • Gas permeability is 3-10 times lower than NBR, ideal for fuel system components.
  • ECO rubber exhibits good chemical resistance to mineral oils and ozone, but poor resistance to ketones.
  • ASTM D2000 classification for ECO rubber is CH/DE, ensuring it meets industry standards.

Industrial applications

  • 1Used in automotive fuel hoses to ensure resistance to fuel permeation.
  • 2Employed in fuel sender unit seals to maintain integrity under various temperatures.
  • 3Utilized in air intake boots requiring flexibility and oil resistance.
  • 4Applied in manufacturing oil-resistant industrial gaskets for various machinery.
  • 5Incorporated into diaphragms for fuel systems to prevent leakage.

Common mistakes

  • Using ECO rubber in applications involving ketones or esters can lead to premature failure.
  • Neglecting to consider the temperature range of ECO rubber can result in material degradation.
  • Overlooking the specific ASTM classifications may lead to inappropriate material selection.
  • Assuming all types of epichlorohydrin rubber have the same chemical resistance properties.
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Pro tip

Always verify the compatibility of ECO rubber with the specific fuels or chemicals it will encounter in your application to avoid failures.

Technical standards

  • ASTM D2000 - Standard Classification System for Rubber Products in Automotive Applications.

Suppliers of industrial materials in Mexico

Applicable standards

ASTM D2000