Full definition
Compression set is a crucial property of elastomers, particularly in sealing applications, where the ability to maintain a seal over time is vital. It refers to the percentage of permanent deformation that remains in an elastomer after it has been compressed under controlled conditions and subsequently released. This property is quantified through standardized testing methods, most commonly ASTM D395: Method B, where a specimen is compressed to 25% of its original thickness and held for a period ranging from 22 to 70 hours at a specified temperature. After this compression period, the specimen is allowed to recover, and its thickness is measured after a 30-minute recovery period. The formula used to calculate the compression set is CS = (t₀ - tᵢ) / (t₀ - tₛ) × 100%, where t₀ represents the original thickness, tᵢ is the recovered thickness, and tₛ is the spacer thickness. Lower compression set values indicate better recovery characteristics, which translates to improved sealing performance.
In practice, different elastomers exhibit varying compression set values at elevated temperatures, such as 100°C over 22 hours. For instance, natural rubber (NR) typically exhibits a compression set of 15-30%, while EPDM ranges from 15-35%. Nitrile rubber (NBR) can have a compression set of 20-40%, and fluorocarbon elastomers (FKM) often fall between 15-30%. Silicone elastomers usually show a compression set of 20-40%. A seal with a high compression set will gradually lose its sealing force, leading to potential leaks as the material fails to return to its original shape.
Post-curing treatments can significantly enhance the performance of elastomers such as FKM and silicone, reducing their compression set by 30-50%. It is crucial to note that temperature and time are significant factors affecting compression set; higher temperatures and prolonged exposure lead to increased compression set values. Therefore, when selecting O-ring and gasket materials, compression set should be the first property to specify to ensure optimal sealing performance over the intended service life.